Lithium dendrites caused by low-temperature charging

SAE J537 is a cold-start performance test standard established by the Society of Automotive Engineers (SAE) for lead-acid batteries. It is primarily used to evaluate the discharge capacity of lead-acid starter batteries in cold environments. However, in recent years, some manufacturers have applied this standard to Lithium Iron Phosphate (LiFePO₄) batteries as a basis for performance claims. This practice is not only technically incorrect but also potentially misleading for consumers.


Content and Purpose of the Test

The core of the SAE J537 test involves:

  • Soaking the battery in a -18°C environment for 24 hours.
  • Performing a high-current discharge (e.g., 150A for 30 seconds).
  • Charging at room temperature.
  • Measuring voltage maintenance and capacity decay.

This protocol is designed to simulate an engine start in cold climates. The target is lead-acid chemistry, and it does not account for the specific charging behaviors or safety risks unique to lithium-ion batteries.


The Critical Risk: Cold Charging and Lithium Dendrites

Lithium batteries face a fatal risk when charged at low temperatures (especially below 0°C): Lithium Plating.

  1. Lithium Plating: During cold charging, lithium ions cannot migrate into the anode fast enough. Instead, they deposit as metallic lithium on the surface of the anode.
  2. Dendrite Growth: As this plating continues, it forms needle-like structures called Dendrites.
  3. Internal Short Circuit: These dendrites can eventually pierce the battery separator, leading to an internal short circuit, thermal runaway, or fire.

The fatal flaw of SAE J537 is that it allows the battery to be charged at room temperature after the cold discharge. This bypasses the most dangerous scenario for a car battery: the alternator charging the lithium battery while the vehicle is driving in sub-zero temperatures.


Conclusion: Don’t Be Fooled by Selective Data

When a manufacturer boasts about passing SAE J537 with a lithium battery, they are following a “promotional script” that avoids the risks of low-temperature charging.

True automotive-grade lithium battery safety should be evaluated based on standards like UL 2580 or IEC 62660, which include rigorous thermal abuse, overcharge, and low-temperature safety tests. Real safety comes from robust Battery Management Systems (BMS) and honest risk disclosure—not selective performance displays that ignore the chemistry’s fundamental vulnerabilities.